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Hi,
It is possible to add (at least) two more UARTs to the efika? Can the PSC6 work as UART?
Yes but it has no CTS line, and PSC6 can't be used as an eUART (Freescale's term for "it has a carrier detect pin") so you will only be able - from the pins on the board at least - use simple RX/TX with no handshake.
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I would like to have the ports with the bare CMOS output voltage (i.e., no rs-232 transceivers), the flow control is not required.
You will be fine, then. Make sure you put some adequate protection on the pins such that you do not fry the boards; some small (1-kohm minimum?) resistor will do.
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Maybe there's some (cheap) PCI card to be fitted into the Efika?
There are lots of PCI serial cards in the world,
very expensive mostly, but some
quite cheap and they should work under Linux. Whether they are 3.3V or not is up to the manufacturer; neither that I linked are 3.3V keyed, so won't even fit, let alone work.
3.3V is not common on PC desktops (in fact it is practically unthinkable). MiniPCI is fixed at 3.3V so they will all work. Either way you will probably end up sourcing a serial port card from some embedded systems company.
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By the way, I successfully used some miniPCI Ralink rt2500 based cards with the pci to minipci adapter. Can I assume that also pci cards based on rt2500 will be 3.3v compliant?
I would not count on it (see above) but check the keying on the board before you buy one, the worst that can happen is the card simply does not appear on the bus. You will not fry anything that has a universal connector but is just a badly designed 5V card.
One thing to look out for is those multiple MiniPCI adapters (2-3 or even 4 slots per PCI slot) as they have a PCI bridge on them, the firmware currently does *not* properly configure PCI bridges, in either transparent or bridge mode, so you may be a little disappointed.